It's the backfire that causes issues with the Catalytic Converter, with just one of your cylinder's misfiring. I would not loose any sleep over it since you have not mentioned any backfires issues.
If you like, you can try adding half a can of
http://www.seafoamsales.com/ in to your gas tank and the rest in through your vacuum tube. (PVC Line) Just to clean out your fuel line and upper intake. Also clean your MAF sensor with MAF sensor cleaner, just follow the instructions on the spray can.
Good luck and keep us posted and let me know what condition your #5 spark plug is. (Driver's side to the back of the engine.) Would help to know if the cylinder is lean or rich.